groundwater geochemistry and isotopes

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Groundwater Geochemistry And Isotopes

Author : Ian Clark
ISBN : 9781466591745
Genre : Science
File Size : 44. 90 MB
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Understand the Environmental Processes That Control Groundwater Quality The integration of environmental isotopes with geochemical studies is now recognized as a routine approach to solving problems of natural and contaminated groundwater quality. Advanced sampling and analytical methods are readily accessible and affordable, providing abundant geochemical and isotope data for high spatial resolution and high frequency time series. Groundwater Geochemistry and Isotopes provides the theoretical understanding and interpretive methods and contains a useful chapter presenting the basics of sampling and analysis. This text teaches the thermodynamic basis and principal reactions involving the major ions, gases and isotopes during groundwater recharge, weathering and redox evolution. Subsequent chapters apply these principles in hands-on training for dating young groundwaters with tritium and helium and ancient systems with radiocarbon, radiohalides and noble gases, and for tracing reactions of the major contaminants of concern in groundwaters. Covers the basics of solutes, gases and isotopes in water, and concentration-activity relationships and reactions Describes tracing the water cycle, weathering, and the geochemical evolution of water quality Explores dating groundwater as young as a few years to over hundreds of millions of years Uses case studies to demonstrate the application of geochemistry and isotopes for contaminated groundwaters Accessible to consultants and practitioners as well as undergraduates, Groundwater Geochemistry and Isotopes presents the basics of environmental isotopes and geochemistry, and provides you with a full understanding of their use in natural and contaminated groundwater.

Groundwater Geochemistry

Author : Broder J. Merkel
ISBN : 3540746684
Genre : Science
File Size : 50. 23 MB
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To understand hydrochemistry and to analyze natural as well as man-made impacts on aquatic systems, hydrogeochemical models have been used since the 1960’s and more frequently in recent times. Numerical groundwater flow, transport, and geochemical models are important tools besides classical deterministic and analytical approaches. Solving complex linear or non-linear systems of equations, commonly with hundreds of unknown parameters, is a routine task for a PC. Modeling hydrogeochemical processes requires a detailed and accurate water analysis, as well as thermodynamic and kinetic data as input. Thermodynamic data, such as complex formation constants and solubility-products, are often provided as databases within the respective programs. However, the description of surface-controlled reactions (sorption, cation exchange, surface complexation) and kinetically controlled reactions requires additional input data. Unlike groundwater flow and transport models, thermodynamic models, in principal, do not need any calibration. However, considering surface-controlled or kinetically controlled reaction models might be subject to calibration. Typical problems for the application of geochemical models are: • speciation • determination of saturation indices • adjustment of equilibria/disequilibria for minerals or gases • mixing of different waters • modeling the effects of temperature • stoichiometric reactions (e.g. titration) • reactions with solids, fluids, and gaseous phases (in open and closed systems) • sorption (cation exchange, surface complexation) • inverse modeling • kinetically controlled reactions • reactive transport Hydrogeochemical models depend on the quality of the chemical analysis, the boundary conditions presumed by the program, theoretical concepts (e.g.

Grundwasserchemie

Author : Broder J. Merkel
ISBN : 9783662076118
Genre : Science
File Size : 21. 53 MB
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Die Autoren konzentrieren sich in ihrem Werk auf die Lösung praxisorientierter hydrogeochemischer Fragestellungen und schließen damit eine Lücke im Bereich anwendungsorientierter Lehrbücher. Ein erster Teil fasst dabei die Theorie soweit zusammen, daß es auch Neulingen im Bereich der Modellierung und Nichtchemikern leicht gemacht wird, das anspruchsvolle Thema zu erfassen. Akademikern mit hydrogeologischer oder chemischer Grundausbildung sowie Studenten höherer Semester in den relevanten Fachgebieten erlaubt das Buch, anhand der beschriebenen Beispiele und Lösungen, eine eigenständige Erarbeitung der Sachverhalte. Die beiliegende CD-ROM ermöglicht zudem eine rasche Überprüfung der Ergebnisse, bzw. das Nachvollziehen aller Aufgaben und Lösungen anhand der beigefügten PhreeC-Eingabedateien. Da das Programm PhreeC kostenfrei verfügbar ist und mit Windows-Oberfläche auf der CD-ROM vorhanden ist, kann sofort mit der Modellierung begonnen werden.

Handbook Of Environmental Isotope Geochemistry

Author : Mark Baskaran
ISBN : 3642106374
Genre : Science
File Size : 35. 66 MB
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Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies.

Environmental Isotopes In Hydrogeology

Author : Ian D. Clark
ISBN : 9781482242911
Genre : Science
File Size : 75. 50 MB
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Groundwater is an increasingly important resource to human populations around the world, and the study and protection of groundwater is an essential part of hydrogeology - the subset of hydrology that concentrates on the subsurface. Environmental isotopes, naturally occurring nuclides in water and solutes, have become fundamental tools for tracing the recharge, history, and contamination of groundwater.

Groundwater Geochemistry

Author : William J. Deutsch
ISBN : 0873713087
Genre : Technology & Engineering
File Size : 68. 31 MB
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Groundwater Geochemistry: Fundamentals and Applications to Contamination examines the integral role geochemistry play s in groundwater monitoring and remediation programs, and presents it at a level understandable to a wide audience. Readers of all backgrounds can gain a better understanding of geochemical processes and how they apply to groundwater systems. The text begins with an explanation of fundamental geochemical processes, followed by a description of the methods and tools used to understand and simulate them. The book then explains how geochemistry applies to contaminant mobility, discusses remediation system design, sampling program development, and the modeling of geochemical interactions. This clearly written guide concludes with specific applications of geochemistry to contaminated sites. This is an ideal choice for readers who do not have an extensive technical background in aqueous chemistry, geochemistry, or geochemical modeling. The only prerequisite is a desire to better understand natural processes through groundwater geochemistry.

Palaeowaters In Coastal Europe

Author : W. M. Edmunds
ISBN : 186239086X
Genre : Science
File Size : 43. 67 MB
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Handbook Of Environmental Isotope Geochemistry The Terrestrial Environment B

Author : Peter Fritz
ISBN : CORNELL:31924072097987
Genre : Science
File Size : 51. 21 MB
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Geochemistry Of The Cambrian Ordovician Aquifer System In The Northern Midwest United States

Author : Donald I. Siegel
ISBN : UIUC:30112113049883
Genre : Aquifers
File Size : 37. 21 MB
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A The Terrestrial Environment

Author : P. Fritz
ISBN : 9781483289618
Genre : Science
File Size : 69. 67 MB
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Handbook of Environmental Isotope Geochemistry, Volume 1: The Terrestrial Environment, A focuses on isotope hydrology and aqueous geochemistry, as well as an overview of carbon, sulfur, and nitrogen isotopes in terrestrial systems. The selection first elaborates on the isotopes of hydrogen and oxygen in precipitation, carbon-14 in hydrogeological studies, and environmental isotopes in groundwater hydrology. Concerns cover groundwater dating, mechanism of salinization, groundwater recharge, models of the isotope fractionation during evaporation and condensation of water in the atmosphere, and stable isotope distribution in atmospheric waters. The book then examines environmental isotopes in ice and snow, isotopic evidence on environments of geothermal systems, and sulfur and oxygen isotopes in aqueous sulfur compounds. Discussions focus on geochemistry and isotope distribution of aqueous sulfur compounds, isotopic dating of geothermal waters, origin of chemical constituents, geothermometry, isotope distribution during the reduction of a temperate snow cover, and snow and ice isotope hydrology. The manuscript explores environmental isotopes as environmental and climatological indicators, sulfur isotopes in the environment, nitrogen-15 in the natural environment, and the isotopic composition of reduced organic carbon. The selection is a valuable reference for researchers interested in isotope geochemistry.

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