metal ligand bonding

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Metal Ligand Bonding

Author : E A Moore
ISBN : 9781847559456
Genre : Education
File Size : 41. 66 MB
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To appreciate the chemistry and physical properties of complexes of the transition series, an understanding of metal-ligand interactions applied to complexes of the d-block is needed. Metal Ligand Bonding aims to provide this through an accessible, detailed, non-mathematical approach. Initial chapters detail the crystal-field model, using it to describe the use of magnetic measurements to distinguish complexes with different electronic configurations and geometries. Subsequent chapters look at the molecular orbital theory of transition metal complexes using a pictorial approach. Bonding in octahedral complexes is explored and electronic spectra and magnetic properties are given extensive coverage. The material addressed in this book forms the foundation of undergraduate lecture courses on d-block chemistry and facilitates learning through various key features, including: full colour diagrams; in-text questions with answers; revision exercises and clearly defined learning outcomes to encourage a reflective approach to study; an associated website; and experimental data and observations from everyday life. A basic knowledge of atomic and molecular orbitals as applied to main group elements is assumed.

Metal Ligand Interactions In Chemistry Physics And Biology

Author : N. Russo
ISBN : 9789401142458
Genre : Science
File Size : 43. 91 MB
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Proceedings of the NATO Advanced Study Institute, held in Cetraro (CS) Italy, from 1-12 September 1998

The Chemical Bond Chemical Bonding Across The Periodic Table

Author : Gernot Frenking
ISBN : 9783527333158
Genre : Science
File Size : 76. 68 MB
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Metal Ligand Bonding Energetics In Organotransition Metal Compounds

Author : Tobin J. Marks
ISBN : UCSD:31822005891551
Genre : Chemical bonds
File Size : 61. 73 MB
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Essentials Of Coordination Chemistry

Author : Vasishta Bhatt
ISBN : 9780128039373
Genre : Science
File Size : 33. 55 MB
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Essentials of Coordination Chemistry: A Simplified Approach with 3D Visuals provides an accessible overview of this key, foundational topic in inorganic chemistry. Thoroughly illustrated within the book and supplemented by online 3D images and videos in full color, this valuable resource covers basic fundamentals before exploring more advanced topics of interest. The work begins with an introduction to the structure, properties, and syntheses of ligands with metal centers, before discussing the variety of isomerism exhibited by coordination compounds, such as structural, geometrical and optical isomerism. As thermodynamics and kinetics provide a gateway to synthesis and reactivity of coordination compounds, the book then describes the determination of stability constants and composition of complexes. Building upon those principles, the resource then explains a wide variety of nucleophilic substitution reactions exhibited by both octahedral and square planar complexes. Finally, the book discusses metal carbonyls and nitrosyls, special classes of compounds that can stabilize zero or even negative formal oxidation states of metal ions. Highlighting preparations, properties, and structures, the text explores the unique type of Metal-Ligand bonding which enable many interesting applications of these compounds. Thoughtfully organized for academic use, Essentials of Coordination Chemistry: A Simplified Approach with 3D Visuals encourages interactive learning. Advanced undergraduate and graduate students, as well as researchers requiring a full overview and visual understanding of coordination chemistry, will find this book invaluable. Includes valuable visual content through 3D images and videos in full color, available online Provides a valuable introduction to the study of organic and inorganic ligands with metal centers Discusses advanced topics including metal carbonyls and nitrosyls

Molecular Orbitals Of Transition Metal Complexes

Author : Yves Jean
ISBN : 0191513695
Genre : Science
File Size : 67. 69 MB
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This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.

Metal Ligand Interactions

Author : Malgorzata Witko
ISBN : 1402014945
Genre : Ligands
File Size : 73. 33 MB
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Investigating The Role Of Metal Ligand Bonding On Biological Activity Of Metallotherapeutics

Author : Thamayanthy Sriskandakumar
ISBN : OCLC:1033019486
Genre :
File Size : 53. 20 MB
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Metal Metal Bonding

Author : Gerard Parkin
ISBN : 9783642052422
Genre : Science
File Size : 42. 58 MB
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Bonding In Tetrahedral Transition Metal Complexes Having Pi Acceptor Ligands

Author : Suzanne Rabitz
ISBN : WISC:89010733566
Genre :
File Size : 76. 21 MB
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