nmr of chemically exchanging systems

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Nmr Of Chemically Exchanging Systems

Author : Jerome Kaplan
ISBN : 9780323160643
Genre : Science
File Size : 24. 59 MB
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NMR of Chemically Exchanging Systems presents an integrated density matrix formalism for calculating NMR lineshapes for all types of exchanging systems. This book explores a variety of conditions, which is applicable to both liquids and liquid crystals. Organized into nine chapters, this book begins with an overview of the derivation of the absorption due to a single spin utilizing the classical Bloch equation as a means for introducing some of the concepts concerned in obtaining the absorption lineshape. This text then examines the derivation of the total density matrix equation. Other chapters consider the density matrix equation for a general exchanging system at high rf power and illustrate how one has to solve for all the elements of the density matrix. The final chapter presents some remarks on transients as applied to chemically exchanging systems. This book is a valuable resource for scientists and researchers who are interested in NMR spectroscopy.

Nuclear Magnetic Resonance

Author : G. A. Webb
ISBN : 9780854043521
Genre : Reference
File Size : 83. 96 MB
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For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage.

Physico Chemical Applications Of Nmr

Author : A. B. Kudryavtsev
ISBN : 9810225407
Genre : Science
File Size : 60. 32 MB
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The book is intended to help under- and postgraduate students and young scientists in the correct application of NMR to the solution of physico-chemical problems concerning the study of equilibria in solution. The first part of the book (Chapters 1-3) is a trivium, but should enable a student to design and conduct simple physico-chemical NMR experiments. The following chapters give illustrative material on the physico-chemical applications of NMR of increasing complexity. These chapters include the problem of determination of equilibrium and rate constants in solution, the study of paramagnetism using NMR, the application of Dynamic NMR techniques and relaxation measurements. A multipurpose nonlinear regression program is supplied (on disc for PC) and is referred to throughout the book.

Chlorine Bromine And Iodine Nmr

Author : B. Lindman
ISBN : 9783642663635
Genre : Science
File Size : 89. 39 MB
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The increasing interest in NMR spectroscopy of what in some confer ences in this field is commonly termed "other nuclei" is unmistakable. Chemists and biologists who employ NMR spectroscopy to study their problems have, however, been somewhat reluctant to study nuclei with electric quadrupole moments. These nuclei frequently give rise to broad NMR signals, sometimes too broad to be detectable with ordinary high resolution NMR spectrometers. Spectrometers that could cope with broad NMR signals of low intensity, "wide-line" spectrometers, have been available since the mid 1950:s but it appears that most of these instruments ended up in physical laboratories where the research was primarily directed towards solid state problems. The study of quadrupolar nuclei can provide unique and very valuable information on a variety of physico-chemical and biological systems. For one thing the relaxation of quadrupolar nuclei is in many ways easier to interpret than the relaxation of non-quadrupolar nuclei, since the former is in many cases caused by purely intramolecular interactions modulated by the molecular motion. Studies of quadrupolar relaxation have therefore furnished important information about molec ular reorientation and association in liquids and have played - and will certainly play for many years - an important role in testing new theoretical models of molecular motion in liquids.

Nmr In Biological Systems

Author : K.V.R. Chary
ISBN : 9781402066801
Genre : Science
File Size : 39. 40 MB
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During teaching NMR to students and researchers, we felt the need for a text-book which can cover modern trends in the application of NMR to biological systems. This book covers the entire area of NMR in Biological Sciences (Biomolecules, cells and tissues, animals, plants and drug design). As well as being useful to researchers, this is an excellent book for teaching a course on NMR in Biological Systems.

Einf Hrung In Die Physikalische Chemie

Author : Heinrich Labhart
ISBN : 9783642694349
Genre : Science
File Size : 25. 30 MB
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Dynamic Nmr Spectroscopy

Author :
ISBN : 9783642669613
Genre : Science
File Size : 62. 76 MB
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Since the first successful NMR experiments in 1946 it was well appreciated that dynamic processes play an important role in the NMR spectroscopy of bulk matter [1]. Early theories on the dependence of the relaxation parameters Tl and T2 on the motions of nuclear spins were successful in explaining the dipolar broadening of the NMR signal in solids and the motional narrowing in liquids [2]. With the discovery of chemical shifts and spin-spin couplings another type of dynamical process affect ing the NMR line shape became apparent, the chemical exchange. As a consequence, dynamical NMR studies split into two groups differing not only in the dynamical topics but also in the method of investigation: physical studies of the motion of spins in liquids and solids by measurement of the relaxation times of single resonances and, on the other hand, chemical studies based on band shape analysis of NMR spectra recorded under steady state conditions. The two fields of research lost some of their basic differences with the development of the Fourier transform NMR method [3], which allows the measurement of relaxation times of different resonances at the same time, i. e. the study of differential motional behavior of different parts of mole cules, thus providing a new tool in conformational analyses. For example, informa tion can be obtained by this method on the relative importance of overall motions and internal motions [4].

Inclusion Chemistry With Zeolites Nanoscale Materials By Design

Author : Norman Herron
ISBN : 0792336062
Genre : Medical
File Size : 54. 68 MB
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Zeolites, with their crystalline microporous structure, are cordial hosts to a wide variety of guests. Traditional absorption techniques, as well as X-ray diffraction and spectroscopic techniques, have contributed to a better understanding of the nature of the host materials' characteristic cavities, cages and channels. The same techniques, coupled with powerful computational methods, have given new insights into the interactions of guest molecules with their hosts. In turn, this has led to new developments in the direction of structure during zeolite synthesis as well as potentially new applications of guest-host materials. The 11 chapters of Inclusion Chemistry with Zeolites: Nanoscale Materials by Design represent the cutting edge of modern research, describing some of the most recent studies on structure direction in synthesis, characterization techniques, computational aspects, coordination and organometallic chemistry, photochemistry, and electronic and optical materials. The diversity and wide utility of its presentation will inspire creative readers to create their own nanoscale materials by design'.

Nmr And Chemistry

Author : J.W. Akitt
ISBN : 0748743448
Genre : Science
File Size : 69. 32 MB
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Keeping mathematics to a minimum, this book introduces nuclear properties, nuclear screening, chemical shift, spin-spin coupling, and relaxation. It is one of the few books that provides the student with the physical background to NMR spectroscopy from the point of view of the whole of the periodic table rather than concentrating on the narrow applications of 1H and 13C NMR spectroscopy. Aids to structure determination, such as decoupling, the nuclear Overhauser effect, INEPT, DEPT, and special editing, and two dimensional NMR spectroscopy are discussed in detail with examples, including the complete assignment of the 1H and 13C NMR spectra of D-amygdain. The authors examine the requirements of a modern spectrometer and the effects of pulses and discuss the effects of dynamic processes as a function of temperature or pressure on NMR spectra. The book concludes with chapters on some of the applications of NMR spectroscopy to medical and non-medical imaging techniques and solid state chemistry of both I = F1/2 and I > F1/2 nuclei. Examples and problems, mainly from the recent inorganic/organometallic chemistry literature support the text throughout. Brief answers to all the problems are provided in the text with full answers at the end of the book.

Annual Reports On Nmr Spectroscopy

Author : Graham A. Webb
ISBN : 9780080970738
Genre : Science
File Size : 84. 28 MB
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Nuclear magnetic resonance (NMR) is an analytical tool used by chemists and physicists to study the structure and dynamics of molecules. In recent years, no other technique has gained such significance as NMR spectroscopy. It is used in all branches of science in which precise structural determination is required and in which the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a premier means for the specialist and non-specialist alike to become familiar with new techniques and applications of NMR spectroscopy. Provides updates on the latest developments in NMR spectroscopy Includes comprehensive review articles Highlights the increasing importance of NMR spectroscopy as a technique for structural determination

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