structural methods in molecular inorganic chemistry inorganic chemistry a textbook series

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Structural Methods In Molecular Inorganic Chemistry

Author : D. W. H. Rankin
ISBN : 9781118462881
Genre : Science
File Size : 35. 70 MB
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Determining the structure of molecules is a fundamental skillthat all chemists must learn. Structural Methods in MolecularInorganic Chemistry is designed to help readers interpretexperimental data, understand the material published in modernjournals of inorganic chemistry, and make decisions about whattechniques will be the most useful in solving particular structuralproblems. Following a general introduction to the tools and concepts instructural chemistry, the following topics are covered indetail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories,illustrating how chemists have applied a broad range of structuraltechniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made betweentheoretical topics and the real world of practicing chemists. Eachchapter concludes with problems and discussion questions, and asupporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is anextensive update and sequel to the successful textbookStructural Methods in Inorganic Chemistry by Ebsworth,Rankin and Cradock. It is essential reading for all advancedstudents of chemistry, and a handy reference source for theprofessional chemist.

Anorganische Strukturchemie

Author : Ulrich Müller
ISBN : 9783663108443
Genre : Science
File Size : 90. 67 MB
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Angesichts des immer mehr anwachsenden Kenntnisstands auf allen na turwissenschaftlichen Gebieten erscheint es unumgänglich, die Wissensver mittlung auf generelle Prinzipien und Gesetzmäßigkeiten zu konzentrieren und Einzeldaten auf wichtige Beispiele zu beschränken. Ein Lehrbuch soll einen angemessenen, dem Studierenden zumutbaren Umfang haben, ohne wesentliche Aspekte eines Fachgebiets zu vernachlässigen, es soll traditio nelles Grundwissen ebenso wie moderne Entwicklungen berücksichtigen. Diese Einführung macht den Versuch, die Anorganische Strukturchemie in diesem Sinne darzubieten. Dabei sind Kompromisse unvermeidbar, manche Teilgebiete werden kürzer, andere vielleicht auch länger geraten sein, als es dem einen oder anderen Fachkollegen angemessen erscheinen mag. Chemiker denken überwiegend in anschaulichen Modellen, sie wollen Strukturen und Bindungen "sehen". Die moderne Bindungstheorie hat sich ihren Platz in der Chemie erobert, sie wird in Kapitel 9 gewürdigt; mit ihren aufwendigen Rechnungen entspricht sie aber mehr der Denkweise des Physikers, außerdem ist sie oft noch unbefriedigend, wenn es darum geht, strukturelle Details zu verstehen oder gar vorauszusagen. Für den Alltags gebrauch des Chemikers sind einfache Modelle, so wie sie in den Kapiteln 7, 8 und 12 behandelt werden, nützlicher: "Der Bauer, der zu Lebzeiten ernten will, kann nicht auf die ab-initio-Theorie des Wetters warten. Che miker, wie Bauern, glauben an Regeln, verstehen aber diese listig nach Bedarf zu deuten" (H.G. von Schnering [86]).

Advancing Pharmaceutical Processes And Tools For Improved Health Outcomes

Author : Gasmelseid, Tagelsir Mohamed
ISBN : 9781522502494
Genre : Medical
File Size : 87. 66 MB
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There has been a growing concern for the improvement of pharmaceutical services provided by healthcare institutions. This concern is also shared by other stakeholders including patients, regulatory organizations, pharmaceutical companies, insurance companies, and research institutions. Advancing Pharmaceutical Processes and Tools for Improved Health Outcomes presents research-based perspectives on the pharmaceutical industry in today’s digitally-fueled world. Focusing on technological innovations for pharmaceutical applications as well as current trends in the industry, this publication is ideally designed for use by pharmacists, medical professionals, administrators in the medical field, health insurance professionals, researchers, and graduate-level students.

Inorganic Structural Chemistry

Author : Ulrich Müller
ISBN : 9780470057261
Genre : Science
File Size : 40. 66 MB
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The essential introduction to the understanding of the structure of inorganic solids and materials. This revised and updated 2nd Edition looks at new developments and research results within Structural Inorganic Chemistry in a number of ways, special attention is paid to crystalline solids, elucidation and description of the spatial order of atoms within a chemical compound. Structural principles of inorganic molecules and solids are described through traditional concepts, modern bond-theoretical theories, as well as taking symmetry as a leading principle.

Applications Of Physical Methods To Inorganic And Bioinorganic Chemistry

Author : Robert A. Scott
ISBN : 9780470032176
Genre : Science
File Size : 23. 74 MB
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Modern spectroscopic and instrumental techniques are essential to the practice of inorganic and bioinorganic chemistry. This text provides a consistent and comprehensive description of the practical aaplicability of a large number of techniques to modern problems in organic and bioinorganic chemistry.

Bioinorganic Chemistry Inorganic Elements In The Chemistry Of Life

Author : Wolfgang Kaim
ISBN : 9781118659267
Genre : Science
File Size : 35. 58 MB
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The field of Bioinorganic Chemistry has grown significantly inrecent years; now one of the major sub-disciplines of InorganicChemistry, it has also pervaded other areas of the life sciencesdue to its highly interdisciplinary nature. Bioinorganic Chemistry: Inorganic Elements in the Chemistryof Life, Second Edition provides a detailed introduction to therole of inorganic elements in biology, taking a systematicelement-by-element approach to the topic. The second edition ofthis classic text has been fully revised and updated to include newstructure information, emerging developments in the field, and anincreased focus on medical applications of inorganic compounds. Newtopics have been added including materials aspects of bioinorganicchemistry, elemental cycles, bioorganometallic chemistry, medicalimaging and therapeutic advances. Topics covered include: Metals at the center of photosynthesis Uptake, transport, and storage of essential elements Catalysis through hemoproteins Biological functions of molybdenum, tungsten, vanadium andchromium Function and transport of alkaline and alkaline earth metalcations Biomineralization Biological functions of the non-metallic inorganicelements Bioinorganic chemistry of toxic metals Biochemical behavior of radionuclides and medical imaging usinginorganic compounds Chemotherapy involving non-essential elements This full color text provides a concise and comprehensive review ofbioinorganic chemistry for advanced students of chemistry,biochemistry, biology, medicine and environmental science.

The Organometallic Chemistry Of N Heterocyclic Carbenes

Author : Han Vinh Huynh
ISBN : 9781118698792
Genre : Science
File Size : 70. 87 MB
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The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

Biological Inorganic Chemistry

Author : Robert R. Crichton
ISBN : 9780444537836
Genre : Science
File Size : 83. 31 MB
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Biological Inorganic Chemistry: A New Introduction to Molecular Structure and Function, Second Edition, provides a comprehensive discussion of the biochemical aspects of metals in living systems. Beginning with an overview of metals and selected nonmetals in biology, the book then discusses the following concepts: basic coordination chemistry for biologists; structural and molecular biology for chemists; biological ligands for metal ions; intermediary metabolism and bioenergetics; and methods to study metals in biological systems. The book also covers metal assimilation pathways; transport, storage, and homeostasis of metal ions; sodium and potassium channels and pumps; magnesium phosphate metabolism and photoreceptors; calcium and cellular signaling; the catalytic role of several classes of mononuclear zinc enzymes; the biological chemistry of iron; and copper chemistry and biochemistry. In addition, the book discusses nickel and cobalt enzymes; manganese chemistry and biochemistry; molybdenum, tungsten, vanadium, and chromium; non-metals in biology; biomineralization; metals in the brain; metals and neurodegeneration; metals in medicine and metals as drugs; and metals in the environment. Winner of a 2013 Textbook Excellence Awards (Texty) from the Text and Academic Authors Association Readable style, complemented by anecdotes and footnotes Enables the reader to more readily grasp the biological and clinical relevance of the subject Color illustrations enable easy visualization of molecular mechanisms

Techniques In Inorganic Chemistry

Author : John P. Fackler, Jr.
ISBN : 1439815151
Genre : Science
File Size : 81. 32 MB
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Inorganic chemistry continues to generate much current interest due to its array of applications, ranging from materials to biology and medicine. Techniques in Inorganic Chemistry assembles a collection of articles from international experts who describe modern methods used by research students and chemists for studying the properties and structures of inorganic chemicals. Crystallography and diffraction methods The book begins by examining developments in small-molecule x-ray crystallography. It identifies some of the major advances, discusses current attitudes toward crystallography and its uses, and considers challenges and future prospects. It then examines how ab initio x-ray powder diffraction (XRPD) methods are used to determine structure, with discussions on metal pyrazolates, metal imidazolates, and metal pyrimidinolates. This is followed by a description of single crystal neutron diffraction, a powerful structural technique. The text highlights what can presently be achieved in neutron diffraction and discusses future applications of neutron scattering. Quantum chemistry Reflecting the popularity of density functional calculations, the book includes a chapter that focuses on quantum chemistry. It examines the latest computational techniques and describes how these techniques can be applied to solve a wide range of real-world problems encountered in the realm of inorganic chemistry and particularly in transition metal chemistry. It also explains the intelligent use of quantum chemical methods for the determination of molecular structure, reactivity, and spectra of coordination and organometallic compounds. Spectroscopy Lastly, the text explores important spectroscopic approaches. It first describes intermolecular nuclear Overhauser effect (NOE) NMR experiments and diffusion experiments, offering examples that demonstrate theoretical aspects of the methodology. The final chapter summarizes recent experimental and theoretical work on pressure effects on the d-d and luminescence spectra of transition metal complexes. Derived from select articles in Comments on Inorganic Chemistry, this volume provides a solid background in the array of techniques available in the researcher’s toolkit.

Practical Approaches To Biological Inorganic Chemistry

Author : Robert R. Crichton
ISBN : 9780444563590
Genre : Science
File Size : 33. 82 MB
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The book reviews the use of spectroscopic and related methods to investigate the complex structures and mechanisms of biological inorganic systems that contain metals. Each chapter presents an overview of the technique including relevant theory, clearly explains what it is and how it works and then presents how the technique is actually used to evaluate biological structures. Practical examples and problems are included to illustrate each technique and to aid understanding. Designed for students and researchers who want to learn both the basics, and more advanced aspects of bioinorganic chemistry. Many colour illustrations enable easier visualization of molecular mechanisms and structures Worked examples and problems are included to illustrate and test the reader’s understanding of each technique Written by a multi-author team who use and teach the most important techniques used today to analyse complex biological structures

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