understanding voltammetry simulation of electrode processes

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Understanding Voltammetry

Author : Richard G Compton
ISBN : 9781783263264
Genre : Science
File Size : 23. 26 MB
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This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion–convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed. Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry. This is the third book in the “Understanding Voltammetry” series, published with Imperial College Press and written by the Compton group. Other books in the series include “Understanding Voltammetry”, written by Richard G Compton with Craig Banks and also “Understanding Voltammetry: Problems and Solutions” (2012) written by Richard G Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies. Contents:IntroductionMathematical Model of an Electrochemical SystemNumerical Solution of the Model SystemDiffusion-Only Electrochemical Problems in One-Dimensional SystemsFirst-Order Chemical Kinetic MechanismsSecond-Order Chemical Kinetic MechanismsElectrochemical Simulation in Weakly Supported MediaHydrodynamic VoltammetryTwo-Dimensional Systems: Microdisc ElectrodesHeterogeneous SurfacesAppendix A: Review of C++Appendix B: Microdisc Program Readership: Graduate students pursuing electrochemistry and electroanalytical studies, as well as researchers and professionals working in the area. Key Features:The first ever textbook teaching experimental electrochemists how to simulateShows how to quantitatively model voltammetryWritten from the Compton Group (Oxford University) with ample experience of electrochemical simulationKeywords:Simulation;Digital Simulation;Numerical Simulation;Electrochemistry;Voltammetry

Understanding Voltammetry

Author : R. G. Compton
ISBN : 1783263237
Genre : Science
File Size : 37. 88 MB
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This is the first textbook in the field of electrochemistry that will teach experimental electrochemists how to carry out simulation of electrode processes. Processes at both macro- and micro-electrodes are examined and the simulation of both diffusion-only and diffusion–convection processes are addressed. The simulation of processes with coupled homogeneous kinetics and at microelectrode arrays are further discussed.Over the course of the book the reader's understanding is developed to the point where they will be able to undertake and solve research-level problems. The book leads the reader through from a basic understanding of the principles underlying electrochemical simulation to the development of computer programs which describe the complex processes found in voltammetry.This is the third book in the “Understanding Voltammetry” series, published with Imperial College Press and written by the Compton group. Other books in the series include “Understanding Voltammetry”, written by Richard G Compton with Craig Banks and also “Understanding Voltammetry: Problems and Solutions” (2012) written by Richard G Compton with Christopher Batchelor-McAuley and Edmund Dickinson. These are and continue to be successful textbooks for graduates in electrochemistry and electroanalytical studies.

Understanding Voltammetry

Author : Richard G. Compton
ISBN : 9781848165861
Genre : Science
File Size : 27. 64 MB
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"There is a wealth of voltammetric data from a range of systems, with numerous diagrams showing actual voltammograms, greatly helpful to a reader new to the field, with underpinning mathematical equations and supportive mechanistic explanation. This is a most useful and instructive book."---Chemistry & Industry --

Electrode Potentials

Author : Richard G. Compton
ISBN : 0198556845
Genre : Science
File Size : 45. 43 MB
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Another winning primer! This new addition to the popular series provides a basic introduction to equilibrium electrochemistry, focusing on electrode potentials and their applications. It builds on a knowledge of elementary thermodynamics giving the student an appreciation of the origin of electrode potentials and shows how these are used to deduce a wealth of chemically important information and data such as equilibrium constants, the free energy, enthalpy and entropy changes of chemical reactions, activity coefficients, the selective sensing of ions. It is mathematically simple, the emphasis throughout is on understanding the foundations of the subject and how it may be used to study problems of chemical interest.

A First Course In Electrode Processes

Author : Derek Pletcher
ISBN : 9781847558930
Genre : Science
File Size : 86. 16 MB
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This user friendly introduction highlights the importance of electrochemistry and its applications to the modern world and the future. In contrast to other texts currently available, it emphasises understanding and avoids using many pages of complex equations. It also describes the diverse applications of electrochemistry rather than focusing on analytical chemistry alone. Although the book follows a similar structure to the first edition, the earlier chapters have been extensively up-dated and the later chapters are entirely new. The text is supported by a large number of figures which illustrate key points. The book starts by describing the essential electrochemical techniques before moving on to cover experimental problems and applications. To reflect the present interest in fuel cells and the environment, these have become the focus of the final chapters. A useful appendix contains problems with fully worked answers to test the reader's understanding.

Introduction To Electrochemistry

Author : D. Brynn Hibbert
ISBN : 9781349227211
Genre : Astronomy
File Size : 50. 57 MB
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An excellent way into the subject'- New Scientist Introduction to Electrochemistry is the first major new text in the field in recent years. The author takes the student from the basics through to a level suitable for beginning a post-graduate course. The chapters cover theory from electrolytes through electrodes to cells, both equilibrium and dynamic. Applications and methods are given great emphasis, and the second part of the text focuses on these aspects with coverage of electrosynthesis, electroanalytical chemistry, industrial electrochemistry, batteries and corrosion. Scattered throughout the text are panels of historical and anecdotal information illustrating unusual and often amusing aspects of electrochemistry not normally presented to the student. This, plus the highly readable style adopted by Brynn Hibbert, and his use of fully worked problems at the end of each chapter, make Introduction to Electrochemistry the ideal undergraduate textbook choice. Introduction to Electrochemistry is part of the Macmillan Physical Sciences Series.

Electrochemical Methods

Author :
ISBN : 8126508078
Genre : Electrochemistry
File Size : 66. 61 MB
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Market_Desc: · Electrochemists· Research Chemists· Analytical Chemists Special Features: · This edition is fully revised to reflect the current state off the field· Significant additions include ultra microelectrodes, modified electrodes, and scanning probe methods· Many chapters have been modified and improved, including electrode kinetics, Volta metric methods, and mechanisms of coupled chemical reactions About The Book: The long-awaited revision of a classic! This widely-used resource takes the reader from the most basic chemical and physical principles through fundamentals of thermodynamics, kinetics, and mass transfer, to a thorough treatment of all important experimental methods. It offers almost full coverage of all important topics in the field, and is renowned for its accuracy and clear presentation.

Electrochemical Strategies In Detection Science

Author : Damien W M Arrigan
ISBN : 9781782622529
Genre : Science
File Size : 62. 63 MB
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Electrochemical methods of chemical analysis have been widely used for many years, most especially the trusty pH electrode and conductivity meter, but also in the mass-manufactured glucose test strips which place electrochemical measurements into the hands of non-scientists. The purpose of this volume is to address advances that will enable new measurement strategies in the future. Surveying research and development advances based on new methods, materials and devices that achieve improved electroanalytical performances, this collection encompasses chip-based systems, through nanodomain approaches and soft interfaces. This book is a vital resource for graduate students and professional analytical chemists.

Analytical Electrochemistry

Author : Joseph Wang
ISBN : 9780471790297
Genre : Science
File Size : 73. 57 MB
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Third Edition covers the latest advances in methodologies, sensors, detectors, and mIcrochips The greatly expanded Third Edition of this internationally respected text continues to provide readers with a complete panorama of electroanalytical techniques and devices, offering a balancebetween voltammetric and potentiometric techniques. Emphasizing electroanalysis rather than physical electrochemistry, readers gain a deep understanding of the fundamentals of electrodereactions and electrochemical methods. Moreover, readers learn to apply their newfoundknowledge and skills to solve real-world analytical problems. The text consists of six expertly crafted chapters: * Chapter 1 introduces fundamental aspects of electrode reactions and the structure of the interfacial region * Chapter 2 studies electrode reactions and high-resolution surface characterization, using techniques ranging from cyclic voltammetry to scanning probe microscopies * Chapter 3 features an overview of modern finite-current controlled potential techniques * Chapter 4 presents electrochemical instrumentation and electrode materials, including modified electrodes and ultramicroelectrodes * Chapter 5 details the principles of potentiometric measurements and various classes of ion selective electrodes * Chapter 6 explores the growing field of chemical sensors, including biosensors, gas sensors, microchip devices, and sensor arrays Among the new topics covered, readers discover DNA biosensors, impedance spectroscopy, detection of capillary electrophoresis, diamond electrodes, carbon-nanotube and nanoparticle-based arrays and devices, large-amplitude AC voltammetry, solid-state ion-selective electrodes, ion selective electrodes for trace analysis, and lab-on-a-chip devices. New figures, worked examples, and end-of-chapter questions have also been added to this edition. Given the rapid pace of discovery and growth of new applications in the field, this text is essential for an up-to-date presentation of the latest advances in methodologies, sensors, detectors, and microchips. It is recommended for graduate-level courses in electroanalytical chemistry and as a supplement for upper-level undergraduate courses in instrumental analysis. The text also meets the reference needs for any industry, government, or academic laboratory engaged in electroanalysis and biosensors.

Springer Handbook Of Electrochemical Energy

Author : Cornelia Breitkopf
ISBN : 9783662466575
Genre : Technology & Engineering
File Size : 83. 53 MB
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This comprehensive handbook covers all fundamentals of electrochemistry for contemporary applications. It provides a rich presentation of related topics of electrochemistry with a clear focus on energy technologies. It covers all aspects of electrochemistry starting with theoretical concepts and basic laws of thermodynamics, non-equilibrium thermodynamics and multiscale modeling. It further gathers the basic experimental methods such as potentiometry, reference electrodes, ion-sensitive electrodes, voltammetry and amperometry. The contents cover subjects related to mass transport, the electric double layer, ohmic losses and experimentation affecting electrochemical reactions. These aspects of electrochemistry are especially examined in view of specific energy technologies including batteries, polymer electrolyte and biological fuel cells, electrochemical capacitors, electrochemical hydrogen production and photoelectrochemistry. Organized in six parts, the overall complexity of electrochemistry is presented and makes this handbook an authoritative reference and definitive source for advanced students, professionals and scientists particularly interested in industrial and energy applications.

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